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Simple Chem Problem

Hey Basil,

I'm having trouble with this problem on setting it up. Its pretty simple but I don't know what equation to use.

1) Calculate the wavelength, and the frequency for the series limit line in the Pfund series for the hydrogen atom.

Thanks for the help =)

March 13, 2013

4 Comments • Newest first

ZOMGitjon

when in doubt put inertia

Reply March 14, 2013
radkai

Is this high school chemistry?

Reply March 14, 2013
Oyster

"series limit" (highest it can go) for hydrogen atom means infinity, and "pfund series" implies n=5
So you are trying to calculate the wavelength and frequency for an emission from ni=infinity to nf=5; or vice versa the amount of energy needed to add in order to remove the electron from the atom:
1/y = -Rh(1/ni^2 - 1/nf^2)
1/y = Rh(1/25) because 1/infinity =0
And frequency can be calculated by the v=c/y relation, where c=2.998 x 10^8 m/s.

Reply March 13, 2013 - edited
flamedagger

Don't you use the Rydberg formula with n=5 for the Pfund series?

Reply March 13, 2013 - edited